The emergence of graphenelike 2d nanostructures has. In this work, graphene oxide nanoribbons gonrs were synthesized by unzipping. Flexible selfcharging supercapacitor based on grapheneag3d. Pdf ultrathin grapheneprotein supercapacitors for miniaturized. Mar 27, 2017 flexible and easily reconfigurable supercapacitors show great promise for application in wearable electronics. To address this problem, we put forward a universal strategy to fabricate substratefree, ultrathin.
Ultrathin planar graphene supercapacitors nano letters. A perspective on twodimensional materials for planar micro. Jun 02, 2014 the resulting planar supercapacitors showed a dramatic increase in capacitance compared to conventional sandwichlike supercapacitors. First, a thin film of graphene oxide go supplementary fig. Pdf nearly all implantable bioelectronics are powered by bulky batteries which limit device miniaturization and lifespan. Sep 12, 20 twodimensional materials have been an ideal material platform for constructing flexible ultrathin film supercapacitors, offering great advantages of flexibility, ultrathinness and even transparency. Nitrogendoped grapheneultrathin mno2 sheet composites ngmcs were prepared through a onestep hydrothermal method at low temperature 120 c. With the advent of atomically thin and flat layers of conducting materials such as graphene, new designs for thin film energy storage devices with good performance have become possible. Scalable fabrication of printed znmno2 planar micro. Graphenebased inplane microsupercapacitors with high. Ultrathin wireless power module with integration of wireless.
Using graphene and 2d materials, new designs for thinfilm planar mscs with outstanding performance have become possible, taking full advantage of their atomic layer thicknesses and flat morphology. Substratefree and shapeless planar microsupercapacitors. Facile synthesis of nitrogendoped grapheneultrathin mno2. The inplane design is straightforward to implement and exploits efficiently the surface of each graphene layer for energy storage. Laserprocessed graphene based microsupercapacitors for. Ultrathin conductive graphitic carbon nitride assembly. The sing thus, the thickness of a supercapacitor is only 8. Graphene supercapacitors store almost as much but charge in just 16 seconds. Figure 1 illustrates the fabrication process of the microsupercapacitors on a silicon wafer. A perspective on twodimensional materials for planar microsupercapacitors apl materials 7, 090902 2019. This cited by count includes citations to the following articles in scholar. Ultrathin wireless power module with integration of. Ultrathin, transparent, and flexible graphene films for supercapacitor application aiping yu, isaac roes, aaron davies, and zhongwei chen.
Advanced solidstate asymmetric supercapacitors based on 3d graphenemno 2 and graphenepolypyrrole hybrid. Recent discoveries regarding innovative device technologies based on tfes flexible. Ultrathin wireless power module with integration of wireless inductive link and supercapacitors chintan buch, p. S1 was obtained by spincoating a go dispersion 2 mg ml. Electronic supplementary information flexible quasisolidstate planar microsupercapacitors based on cellular graphene films 1, 2, 3yuanlong shao, 2jianmin li 4yaogang li, 2hongzhi wang, 2qinghong zhang 1, 5richard b. The development of viable printing technologies has also provided better means for manufacturing, bringing microsupercapacitors closer to practical applications. A team of researchers at the university of minnesota and northwestern university, usa, have developed a printing method to produce flexible graphene microsupercapacitors with a planar architecture suitable for integration in portable electronic devices the new process, referred to as selfaligned capillarityassisted lithography for electronics scale, begins with the creation of a. This study reports the preparation of ultrathin, transparent graphene. Implementation of graphene in supercapacitor electrodes 1. Graphenebased inplane microsupercapacitors with high power and energy densities. A new printing method produces flexible graphene micro.
Ultrathin zns nanosheetcarbon nanotube hybrid electrode for. It is widely regarded as a wonder material because it is endowed with an abundance of astonishing traits. The past decade has witnessed explosive developments of 2d materials and outstanding achievements of planar mscs. Laserprocessed graphene based microsupercapacitors for ultrathin, rollable, compact and designable energy storage components. Flexible ultrathin microsupercapacitors based on laser. Flexible quasisolidstate planar microsupercapacitors. Ultrathin twodimensional mno 2 graphene hybrid nanostructures for highperformance, flexible planar supercapacitors. Ngmcs electrode exhibited enhanced capacitive performances relative to those of undoped grapheneultrathin mno2. Graphene, with unique twodimensional form and numerous appealing properties, promises to remarkably increase the energy density and power density of electrochemical energy storage devices eesds, ranging from the popular lithium ion batteries and supercapacitors to nextgeneration highenergy batteries. Electric doublelayer capacitors, also known as supercapacitors or ultracapacitors. This technique is ideal for fabrication of ultrathin planar microsupercapacitors since it allows for the deposition of a very thin graphene patterns.
It can be fabricated in a large scale and is readily applicable for wearable and. Ultrathin coaxial fiber supercapacitors achieving high energy and. Implementation of graphene in supercapacitor electrodes boris dyatkin1, majid. Due to ultrathin thickness, large surface area, abundant active sites, outstanding. Pdf graphenebased thin film supercapacitor with graphene oxide.
The development of viable printing technologies has also provided better means for manufacturing, bringing micro supercapacitors closer to practical applications. Graphene is a thin layer of pure carbon, tightly packed and bonded together in a hexagonal honeycomb lattice. The flexible ultrathin allsolidstate supercapacitors with good electrochemical and mechanical performance were fabricated by the facile methods. A perspective on twodimensional materials for planar. Graphenebased supercapacitors may significantly boost the power of electric vehicles. Microwaveanionexchange route to ultrathin cobaltnickelsulfide nanosheets for hybrid supercapacitors souleymen rafai, chen qiao, muhammad naveed, zhitao wang, waqar. Ultrathin mno2 sheets were welldispersed and tightly anchored on graphene sheets, which were doped with nitrogen simultaneously. The device architecture offers an enhanced interaction of the electrolyte with carbon layers, leading to a good utilization of the high speci. Ultrathin, transparent, and flexible graphene films for. Polyanilineassisted growth of mno2 ultrathin nanosheets. Ultrathin zns nanosheetcarbon nanotube hybrid electrode. To enhance the energy density of supercapacitors, an asymmetric supercapacitor was prepared by wellmatched email protected 2 nanosheets email protected 2 as cathode material and porous graphene as anode material. The ones marked may be different from the article in the profile.
Flexible and easily reconfigurable supercapacitors show great promise for application in wearable electronics. Graphene performs well as a supercapacitor material because of its high theoretical speci. Ultrathin twodimensional mno2graphene hybrid nanostructures for highperformance, flexible planar supercapacitors. Electrochemical properties of graphene oxide nanoribbons. Ultrathin planar graphene supercapacitors university of. Multilayer graphene synthesized using magnetron sputtering. Flexible and integrated microsupercapacitors based on. Therefore, graphene with highconductivity, flat morphology, good fabricability, and moderate functional groups is promising for highperformance mscs based on interdigital planar structures. Pdf ultrathin planar graphene supercapacitors anchal. Pdf ultrathin twodimensional mno 2 graphene hybrid. Microwaveanionexchange route to ultrathin cobaltnickel.
Shuanghao zheng, xingyan tang, zhongshuai wu, yuanzhi tan, sen wang, chenglin sun, huiming cheng and xinhe bao, arbitraryshaped graphene based planar sandwich supercapacitors on one substrate with enhanced flexibility and integration, acs nano, 10. Ultrathin twodimensional mno2 graphene hybrid nanostructures for highperformance, flexible planar supercapacitors. Nanolett ultrathin planar graphene supercapacitors jung joon yoo,, kaushik balakrishnan, jingsong huang, vincent meunier. The hierarchical mno 2 ultrathin nanosheets uniformly decorating on graphene sheets were prepared by polyanilineassisted growth method.
Chenglin sun, huiming cheng and xinhe bao, arbitraryshaped graphenebased planar sandwich supercapacitors on one substrate with enhanced flexibility and integration, acs nano, 10. Graphene, supercapacitor, inplane geometry, singlelayer graphene, multilayer graphene. According to the configurations and thicknesses of tfes, various electrode processing approaches with particular emphasis on the electrochemical behavior are analyzed. Ultrathin planar graphene supercapacitors university of arizona. Combining the ultrathin structure and unique properties of graphene and 2d materials, we are of great interest in designing and creating highefficient, lowcost, environmentally friendly, advanced energy batteries, e. Pdf graphene for batteries, supercapacitors and beyond. Markondeya raj, billyde brown, himani sharma, teng sun, kyoungsik moon.
This technique is ideal for fabrication of ultrathin planar micro supercapacitors since it allows for the deposition of a very thin graphene patterns. Ultrathin coaxial fiber supercapacitors achieving high. A theoretical assessment, carbon on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Since 2015, westfield technology group have been researching the application of graphene supercapacitors for deployment in their autonomous and human driver interface hdi evs. The novel ultrathin planar devices delivered a specific capacitance of.
A team of researchers at the university of minnesota and northwestern university, usa, have developed a printing method to produce flexible graphene micro supercapacitors with a planar architecture suitable for integration in portable electronic devices. Graphene based supercapacitors with improved specific capacitance and fast charging time at high current density santhakumar akannappan, karthikeyan kaliyappanb,c, rajesh kumar maniand, amaresh samuthira a,pandianb, bhao yange, yun sung lee, jaehyung jang f and wu lua,e. Twodimensional materials have been an ideal material platform for constructing flexible ultrathinfilm supercapacitors, offering great advantages. Sep 10, 2019 the cvd graphene and eg nanosheets are limited by their poor processability. Graphene based supercapacitors with improved specific. Graphenebased inplane microsupercapacitors with high power. This is a pdf file of an unedited manuscript that has been accepted for publication. Graphene is widely applied in the field of energy such as in batteries, supercapacitors, and solar cells.
Microsupercapacitors based on laserreduced graphene with an ultrathin thickness of 20 m exhibit a very high area. Ultrathin planar graphene supercapacitors nano letters acs. Chenglin sun, huiming cheng and xinhe bao, arbitraryshaped graphene based planar sandwich supercapacitors on one substrate with enhanced flexibility and integration, acs nano, 10. Read tailoring the performance of graphenebased supercapacitors using topological defects. Polyanilineassisted growth of mno2 ultrathin nanosheets on. It typically stores 10 to 100 times more energy per unit volume or mass than electrolytic capacitors, can accept and deliver charge much. To address this problem, we put forward a universal strategy to fabricate substratefree, ultrathin, shapeless planar mscs with high performance tenability under serious. Ultrathin printable graphene supercapacitors with ac line. The laser processed graphene based microplanar supercapacitor lpgmps component showed 3.
Micro supercapacitors mscs, albeit powerful are unable to broaden their potential applications primarily because they are not as flexible and shape diverse as electronics. Graphene based supercapacitors with improved specific capacitance and fast charging time at high current density santhakumar akannappan, karthikeyan kaliyappanb,c, rajesh kumar maniand, amaresh samuthira a,pandianb, bhao yange, yun sung lee. A supercapacitor sc, also called an ultracapacitor, is a highcapacity capacitor with a capacitance value much higher than other capacitors, but with lower voltage limits, that bridges the gap between electrolytic capacitors and rechargeable batteries. Materials chemistry a case school of engineering case western. The properties of graphene can be further improved by making nanocomposites with conducting polymers. Here, we report an inplane fabrication approach for ultrathin supercapacitors based on electrodes comprised of pristine graphene and multilayer reduced graphene oxide. Graphene is a robust and attractive electrode material for supercapacitors because of its excellent electrical conductivity, high surfacetovolume ratio, and outstanding intrinsic doublelayer capacitance 21. Using a combination of exfoliated graphene and entangled multiwalled carbon nanotubes combined with plastic, paper and a gelled electrolyte, researchers have developed flexible, solid. Micro supercapacitors based on laserreduced graphene with an ultrathin thickness of 20 m exhibit a very high area. Ultrathin twodimensional mno2graphene hybrid nanostructures. Microsupercapacitors mscs are important onchip micropower sources for miniaturized integrated electronics.
Implementation of graphene in supercapacitor electrodes. Ultrathin planar graphene supercapacitors american chemical. Flexible ultrathin allsolidstate supercapacitors springerlink. Micro supercapacitors based on a 3d structure with. Microwaveanionexchange route to ultrathin cobaltnickelsulfide nanosheets for hybrid supercapacitors souleymen rafai1, chen qiao1, muhammad naveed1, zhitao wang1, waqar younas1and syed. Moreover, the allsolidstate supercapacitors showed an ultrahigh. Photolithographic fabrication of highperformance allsolidstate graphenebased planar microsupercapacitors with different interdigital fingers.
Twodimensional vanadyl phosphate ultrathin nanosheets for. Graphene supercapacitor westfield autonomous vehicles. The resulting planar supercapacitors showed a dramatic increase in capacitance compared to conventional sandwichlike supercapacitors. Outstanding performance of activated graphene based supercapacitors in ionic liquid electrolyte from. Ultrathin planar graphene supercapacitors request pdf. Here, we report an inplane fabrication approach for ultrathin supercapacitors based on. Micro supercapacitors based on a 3d structure with symmetric. This perspective article first summarizes the active materials and electrolytes used for thinfilm electrode tfebased supercapacitors. Polyanilineassisted growth of mno 2 ultrathin nanosheets on graphene and porous graphene for asymmetric supercapacitor with enhanced energy. Graphene is a highly studied material due to its unique electrical, optical, and mechanical properties.